Q. The formation of micelles takes place only above
-
(A)
Inversion temperature
-
(B)
Boyleβs temperature
-
(C)
Critical temperature
-
(D)
Kraft temperature
β
Correct Answer: (D)
Kraft temperature
Q. Colloidion is 4% solution of which one of the following in alcohol-ether mixture.
-
(A)
Nitrocellulose
-
(B)
Glycol dinitrate
-
(C)
Cellulose acetate
-
(D)
Nitroglycerin
β
Correct Answer: (A)
Nitrocellulose
Q. A plot of log xm vs log p for adsorption of gas on a solid gives in straight line with slope equal to
-
(A)
n
-
(B)
1n
-
(C)
log k
-
(D)
-log k
β
Correct Answer: (B)
1n
Q. The protective power of lyophilic colloidal sol is expressed in terms of
-
(A)
oxidation numbers
-
(B)
CMC (Critical Micelle Concentration)
-
(C)
gold number
-
(D)
coagulation value
β
Correct Answer: (C)
gold number
Q. The coagulation values in millimoles per litre of the electrolyte for the coagulation of As2S3 sol are given
I. NaCl (52)
II. BaCl2 (0.69)
III. MgSO4 (0.22)
The correct order of coagulating power is
-
(A)
I > II > III
-
(B)
II > I > III
-
(C)
III > II > I
-
(D)
III > I > II
β
Correct Answer: (C)
III > II > I
Q. According to Freundlich adsorption isotherm, which of the following is correct?
-
(A)
\(\frac{x}{m}\) β p1
-
(B)
\(\frac{x}{m}\) β p1/n
-
(C)
\(\frac{x}{m}\) β pΒ°
-
(D)
All are correct of different ranges of pressure
β
Correct Answer: (D)
All are correct of different ranges of pressure
Q. 3g of activated charcoal was added to 50 ml of acetic acid solution (0.06 M) in a flask. After an hour it was filtered and the strength of filtrate was found to be 0.042 M. The amount of acetic acid adsorbed per gram of charcoal is
-
(A)
42 mg
-
(B)
54 mg
-
(C)
18 mg
-
(D)
36 mg
β
Correct Answer: (B)
54 mg
Q. During the adsorption of gas on the surface of solid, which of the following is true?
-
(A)
βG < 0, βH > 0, βS < 0
-
(B)
βG > 0, βH < 0, βS < 0
-
(C)
βG < 0, βH < 0, βS < 0
-
(D)
βG < 0, βH < 0, βS > 0
β
Correct Answer: (C)
βG < 0, βH < 0, βS < 0
Q. The best coagulant for the precipitation of Fe(OH)3 sol is
-
(A)
Na2HPO3
-
(B)
NaNO3
-
(C)
Na3PO4
-
(D)
Na2SO4
β
Correct Answer: (C)
Na3PO4
Q. Which is favourable for physical adsorption?
-
(A)
High T and high P
-
(B)
High T and low P
-
(C)
Low T and high P
-
(D)
T and P do not affect
β
Correct Answer: (C)
Low T and high P
Q. Identify the positively charged colloid.
-
(A)
Haemoglobin
-
(B)
Clay
-
(C)
Gold sol
-
(D)
As2S3
β
Correct Answer: (A)
Haemoglobin
Q. The stability of lyophobic sols is due to
-
(A)
adsorption of covalent molecules on the colloid
-
(B)
the size of the particles
-
(C)
the charge on particles
-
(D)
Tyndall effect.
β
Correct Answer: (C)
the charge on particles
Q. Gold sol can be prepared by
-
(A)
Hydrolysis of AUCl
-
(B)
Oxidation of Gold by aqua-regia
-
(C)
Peptization
-
(D)
Reduction of AUCl3 with HCHO solution.
β
Correct Answer: (D)
Reduction of AUCl3 with HCHO solution.
Q. The term βsorptionβ stands for ___________ .
-
(A)
absorption
-
(B)
adsorption
-
(C)
desorption
-
(D)
both absorption and adsorption
β
Correct Answer: (D)
both absorption and adsorption
Q. Extent of adsorption of adsorbate from solution phase increases with ___________ .
-
(A)
increase in amount of adsorbate in solution.
-
(B)
increase in temperature of solution.
-
(C)
decrease in amount of adsorbate in solution.
-
(D)
decrease in surface area of adsorbent.
β
Correct Answer: (A)
increase in amount of adsorbate in solution.
Q. Physical adsorption of a gaseous species may change to chemical adsorption with ___________ .
-
(A)
decrease in temperature
-
(B)
increase in surface area of adsorbent
-
(C)
decrease in surface area of adsorbent
-
(D)
increase in temperature
β
Correct Answer: (D)
increase in temperature
Q. On the basis of data given below predict which of the following gases shows least adsorption on a definite amount of charcoal?
-
(A)
CO2
-
(B)
SO2
-
(C)
CH4
-
(D)
H2
β
Correct Answer: (B)
SO2
Q. In which of the following reactions heter-ogenous catalysis is involved?
-
(A)
(ii), (iii)
-
(B)
(ii), (iii), (iv)
-
(C)
(i), (ii), (iii)
-
(D)
(iv)
β
Correct Answer: (A)
(ii), (iii)
Q. In Freundlich adsorption isotherm x/m = Kp1/n, the value of ‘n’ at low pressure is
-
(A)
more than one.
-
(B)
equal to one
-
(C)
from zero to one.
-
(D)
less than one.
β
Correct Answer: (B)
equal to one
Q. According to adsorption theory of catalysis, the speed of the reaction increases because
-
(A)
the concentration of the reactant molecules at the active centres of the catalyst becomes high due to adsorption.
-
(B)
in the process of adsoption, the activation energy of the molecules becomes large.
-
(C)
adsorption produces heat which increases the speed of the reaction.
-
(D)
adsorption lowers the activation energy of the reaction.
β
Correct Answer: (D)
adsorption lowers the activation energy of the reaction.
Q. Which shape selective catalyst is used to convert alcohol to gasoline?
-
(A)
Trpsin
-
(B)
Calgon
-
(C)
ZSM-5
-
(D)
Zeigler-Natta catalyst
β
Correct Answer: (C)
ZSM-5
Q. When a small amount of FeCl3 is added to a freshly precipitated Fe(OH)3, b reddish brown colloidal solution is obtained. This pheno¬menon is known as
-
(A)
dissolution
-
(B)
protection
-
(C)
peptization
-
(D)
dialysis
β
Correct Answer: (B)
protection
Q. Lyophillic colloids are stable due to
-
(A)
charge on the particles.
-
(B)
large size of the particles.
-
(C)
small size of the particles.
-
(D)
layer of dispersion of medium on the particles.
β
Correct Answer: (D)
layer of dispersion of medium on the particles.
Q. Cottrell precipitator is used to
-
(A)
precipitate mud from muddy water.
-
(B)
precipitate carbon particles from smoke.
-
(C)
purify the ordinary drinking water.
-
(D)
precipitate salts in qualitative analysis.
β
Correct Answer: (B)
precipitate carbon particles from smoke.
Q. The potential difference between the fixed charged layer and the diffused layer having opposite charge is called
-
(A)
Zeta potential
-
(B)
Electrokinetic potential
-
(C)
Both A and B
-
(D)
Streaming potential
β
Correct Answer: (A)
Zeta potential
Q. Peptization is a process of
-
(A)
precipitation of colloidal particles.
-
(B)
purification of colloids.
-
(C)
dispersing precipitate into colloidal solution.
-
(D)
movement of colloidal particles in the electric field.
β
Correct Answer: (C)
dispersing precipitate into colloidal solution.
Q. An emulsifier is a substance which
-
(A)
stabilises the emulsion.
-
(B)
homogenises the emulsion.
-
(C)
Coagulates the emulsion.
-
(D)
Accelerates the disperson of liquid in liquid.
β
Correct Answer: (A)
stabilises the emulsion.
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