Solutions MCQs with answers

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Q. The molal elevation constant depends upon
  • (A) nature of solute.
  • (B) nature of the solvent.
  • (C) vapour pressure of the solution.
  • (D) enthalpy change.
💬 Discuss
✅ Correct Answer: (B) nature of the solvent.
Q. The van’t Hoff factor (i) accounts for
  • (A) degree of solubilisation of solute.
  • (B) the extent of dissociation of solute.
  • (C) the extent of dissolution of solute.
  • (D) the degree of decomposition of solution.
💬 Discuss
✅ Correct Answer: (B) the extent of dissociation of solute.
Q. People add sodium chloride to water while boiling eggs. This is to
  • (A) decrease the boiling point.
  • (B) increase the boiling point.
  • (C) prevent the breaking of eggs.
  • (D) make eggs tasty.
💬 Discuss
✅ Correct Answer: (B) increase the boiling point.
Q. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be
  • (A) 0.33
  • (B) 0.666
  • (C) 0.3 × 10-2
  • (D) 3
💬 Discuss
✅ Correct Answer: (C) 0.3 × 10-2
Q. Which has the lowest boiling point at 1 atm pressure?
  • (A) 0.1 M KCl
  • (B) 0.1 M CaCl2
  • (C) 0.1 M A1Cl3
  • (D) 0.1 M Urea
💬 Discuss
✅ Correct Answer: (D) 0.1 M Urea
Q. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows
  • (A) no deviation from Raoult’s Law.
  • (B) negative deviation from Raoult’s Law.
  • (C) positive deviation from Raoult’s Law.
  • (D) that the solution is unsaturated.
💬 Discuss
✅ Correct Answer: (C) positive deviation from Raoult’s Law.
Q. The molality of pure water is
  • (A) 55.5
  • (B) 50.5
  • (C) 18
  • (D) 60.5
💬 Discuss
✅ Correct Answer: (A) 55.5
Q. The number of moles of NaCl in 3 litres of 3M solution is
  • (A) 1
  • (B) 3
  • (C) 9
  • (D) 27
💬 Discuss
✅ Correct Answer: (C) 9
Q. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the resultant solution is ________ .
  • (A) 0.004
  • (B) 0.008
  • (C) 0.012
  • (D) 0.016
💬 Discuss
✅ Correct Answer: (D) 0.016
Q. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to _________ .
  • (A) low temperature
  • (B) high atmospheric pressure
  • (C) low atmospheric pressure
  • (D) both low temperature and high atmospheric pressure
💬 Discuss
✅ Correct Answer: (C) low atmospheric pressure
Q. Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
  • (A) Methanol and acetone.
  • (B) Chloroform and acetone.
  • (C) Nitric acid and water.
  • (D) Phenol and aniline.
💬 Discuss
✅ Correct Answer: (A) Methanol and acetone.
Q. Which of the following aqueous solutions should have the highest boiling point?
  • (A) 1.0 M NaOH
  • (B) 1.0 M NH4NO3
  • (C) 1.0 M KNO3
  • (D) 1.0 M Na2SO4
💬 Discuss
✅ Correct Answer: (D) 1.0 M Na2SO4
Q. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is _________ .
  • (A) the same
  • (B) about twice
  • (C) about three times
  • (D) about six times
💬 Discuss
✅ Correct Answer: (C) about three times
Q. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _________ .
  • (A) it gains water due to osmosis.
  • (B) it loses water due to reverse osmosis.
  • (C) it gains water due to reverse osmosis.
  • (D) it loses water due to osmosis.
💬 Discuss
✅ Correct Answer: (B) it loses water due to reverse osmosis.
Q. The value of Henry’s constant KH is _________
  • (A) greater for gases with higher solubility.
  • (B) constant for all gases.
  • (C) greater for gases with lower solubility.
  • (D) not related to the solubility of gases.
💬 Discuss
✅ Correct Answer: (C) greater for gases with lower solubility.
Q. Consider the figure and mark the correct option.
  • (A) water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on piston (B).
  • (B) water will move from side (B) to side (A) if a pressure greater than osmotic , pressure is applied on piston (B).
  • (C) water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on piston (B).
  • (D) water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston (A).
💬 Discuss
✅ Correct Answer: (B) water will move from side (B) to side (A) if a pressure greater than osmotic , pressure is applied on piston (B).
Q. Which has the highest freezing point?
  • (A) 1 M glucose
  • (B) 1 M NaCl
  • (C) 1 M CaCl2
  • (D) 1 M AlF3
💬 Discuss
✅ Correct Answer: (A) 1 M glucose
Q. Out of molality (m), molarity (M), formality (F) and mole fraction (x), those which are independent of temperature are
  • (A) M, m
  • (B) F, x
  • (C) m, x
  • (D) M, x
💬 Discuss
✅ Correct Answer: (C) m, x
Q. Which of the following condition is not satisfied by an ideal solution?
  • (A) ΔHmixing = 0
  • (B) ΔVmixing = 0
  • (C) Raoult’s Law is obeyed
  • (D) Formation of an azeotropic mixture
💬 Discuss
✅ Correct Answer: (D) Formation of an azeotropic mixture
Q. If molality of dilute solution is doubled, the value of molal depression constant (Kf) will be
  • (A) halved
  • (B) tripled
  • (C) unchanged
  • (D) doubled
💬 Discuss
✅ Correct Answer: (C) unchanged
Q. At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If Kb is 0.52 K/m, the boiling point of solution will be
  • (A) 102°C
  • (B) 101 °C
  • (C) 103°C
  • (D) 100°C
💬 Discuss
✅ Correct Answer: (B) 101 °C
Q. What is mole fraction of solute in 1.00 m aqueous solution?
  • (A) 0.0354
  • (B) 0.0177
  • (C) 0.177
  • (D) 1.770
💬 Discuss
✅ Correct Answer: (B) 0.0177
Q. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 0.01M and 0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the order __________ .
  • (A) iA < iB < iC
  • (B) iA > iB > iC
  • (C) iA = iB = iC
  • (D) iA < iB > iC
💬 Discuss
✅ Correct Answer: (C) iA = iB = iC
Q. A solution containing 10 g per dm3 of urea (molar mass 60 g mol-1) is isotonic with 5% solution of non-volatile solute, MB of solute is
  • (A) 300 g mol-1
  • (B) 350 g mol-1
  • (C) 200 g mol-1
  • (D) 250 g mol-1
💬 Discuss
✅ Correct Answer: (A) 300 g mol-1

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Table of contents

  1. The molal elevation constant depends upon
  2. The van’t Hoff factor (i) accounts for
  3. People add sodium chloride to water while boiling eggs. This is to
  4. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/l
  5. Which has the lowest boiling point at 1 atm pressure?
  6. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethan
  7. The molality of pure water is
  8. The number of moles of NaCl in 3 litres of 3M solution is
  9. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the
  10. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ___
  11. Considering the formation, breaking and strength of hydrogen bond, predict which of the following mi
  12. Which of the following aqueous solutions should have the highest boiling point?
  13. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl
  14. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _________
  15. The value of Henry’s constant KH is _________
  16. Consider the figure and mark the correct option.
  17. Which has the highest freezing point?
  18. Out of molality (m), molarity (M), formality (F) and mole fraction (x), those which are independent
  19. Which of the following condition is not satisfied by an ideal solution?
  20. If molality of dilute solution is doubled, the value of molal depression constant (Kf) wi
  21. At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If K
  22. What is mole fraction of solute in 1.00 m aqueous solution?
  23. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations
  24. A solution containing 10 g per dm3 of urea (molar mass 60 g mol-1) is isotoni