Atoms MCQs with answers

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Q. If 13.6 eV energy is required to ionise the hydrogen atom, then energy required to remove an electron from n = 2 is
  • (A) 10.2 eV
  • (B) 0 eV
  • (C) 3.4 eV
  • (D) 6.8 eV.
💬 Discuss
✅ Correct Answer: (C) 3.4 eV
Q. In Bohr’s model of an atom which of the following is an integral multiple of h2π?
  • (A) Kinetic energy
  • (B) Radius of an atom
  • (C) Potential energy
  • (D) Angular momentum
💬 Discuss
✅ Correct Answer: (D) Angular momentum
Q. In Bohr’s model, the atomic radius of the first orbit is rQ. Then, the radius of the third orbit is
  • (A) r0/9
  • (B) r0
  • (C) 9r0
  • (D) 3r0

💬 Discuss
✅ Correct Answer: (C) 9r0
Q. The ratio between Bohr radii is
  • (A) 1 : 2 : 3
  • (B) 2 : 4 : 6
  • (C) 1 : 4 : 9
  • (D) 1 : 3 : 5
💬 Discuss
✅ Correct Answer: (C) 1 : 4 : 9
Q. The longest wavelength in Balmer series of hydrogen spectrum will be
  • (A) 6557 Å
  • (B) 1216 Å
  • (C) 4800 Å
  • (D) 5600 Å
💬 Discuss
✅ Correct Answer: (A) 6557 Å
Q. In terms of Rydberg constant R, the wave number of the first Balmer line is
  • (A) R
  • (B) 3R
  • (C) 5R36
  • (D) 8R9
💬 Discuss
✅ Correct Answer: (C) 5R36
Q. The ionisation energy of hydrogen atom is 13.6 eV. Following Bohr’s theory the energy corresponding to a transition between 3rd and 4th orbits is
  • (A) 3.40 eV
  • (B) 1.51 eV
  • (C) 0.85 eV
  • (D) 0.66 eV
💬 Discuss
✅ Correct Answer: (D) 0.66 eV
Q. On moving up in the energy states of a H-like atom, the energy difference between two consecutive energy states
  • (A) decreases
  • (B) increases
  • (C) first decreases then increases.
  • (D) first increases then decreases.
💬 Discuss
✅ Correct Answer: (A) decreases
Q. The Bohr model for the spectra of a H-atom
  • (A) will be applicable to hydrogen in the molecular from.
  • (B) will not be applicable as it is for a He- atom.
  • (C) is valid only at room temperature.
  • (D) predicts continuous as well as discrete spectral lines.
💬 Discuss
✅ Correct Answer: (B) will not be applicable as it is for a He- atom.
Q. Consider aiming a beam of free electrons towards free protons. When they scatter, an electron and a proton cannot combine to produce a H-atom,
  • (A) because of energy loss.
  • (B) without simultaneously releasing energy in the from of radiation.
  • (C) because of momentum conservation.
  • (D) because of angular momentum conservation.
💬 Discuss
✅ Correct Answer: (B) without simultaneously releasing energy in the from of radiation.
Q. The binding energy of a H-atom, considering an electron moving around a fixed nuclei (proton), is
B=−me48n2ε20h2. (m = electron mass)
If one decides to work in a frame of reference where the electron is at rest, the proton would be moving arround it. By similar arguments, the binding energy would be
B=−Me48n2ε20h2(M= proton mass)
This last expression is not correct because
  • (A) n would not be integral
  • (B) Bohr-quantisation applies only to electron.
  • (C) the frame in which the electron is at rest is not inertial.
  • (D) the motion of the proton would not be in circular orbits, even approximately.
💬 Discuss
✅ Correct Answer: (C) the frame in which the electron is at rest is not inertial.
Q. The electrons in the Bohr’s orbit have
  • (A) K.E. greater than P.E.
  • (B) P.E. greater than K.E.
  • (C) the same values
  • (D) none of these
💬 Discuss
✅ Correct Answer: (A) K.E. greater than P.E.
Q. For ionising an exicited hydrogan atom, the energy required (in eV) will be
  • (A) a little less than 13.6 eV
  • (B) 13.6 eV
  • (C) more than 13.6 eV
  • (D) 3.4 or less
💬 Discuss
✅ Correct Answer: (D) 3.4 or less
Q. The Bohr model of an atom
  • (A) assumes that the angular momentum of electrons is quantised
  • (B) uses Einstein’s potoelectric equation.
  • (C) predicts continuous emission spectra for atoms,
  • (D) predicts the same emission spectra for all types of atoms.
💬 Discuss
✅ Correct Answer: (A) assumes that the angular momentum of electrons is quantised
Q. Let En=−18ε20me4n2h2 be the energy of the nth level of H-atom. If all the H-atoms are in the ground state and radiation of frequency (E2 – E1)/h falls on it,
  • (A) it will not be absorbed at all.
  • (B) some of atoms will move to the first excited state.
  • (C) all atoms will be excited to the n = 2 state.
  • (D) all atoms will make a transition to the n = 3 state.
💬 Discuss
✅ Correct Answer: (D) all atoms will make a transition to the n = 3 state.
Q. The Balmer series for the H-atom can be observed
  • (A) if we measure the frequencies of light emitted when an excited atom falls to the ground state.
  • (B) if we measure the frequencies of light emitted due to transitions between excited states and the first excited state.
  • (C) in any transition in a H-atom.
  • (D) as a sequence of frequencies with the lower frequencies getting closely packed.
💬 Discuss
✅ Correct Answer: (B) if we measure the frequencies of light emitted due to transitions between excited states and the first excited state.
Q. An ionised H-molecule consists of an electron and two protons. The protons are separated by a small distance of the order of angstrom. In the ground state,
  • (A) the electron would move in circular orbits.
  • (B) the energy would be (2)4 times that of a H-atom.
  • (C) the electrons, orbit would go around the protons.
  • (D) the molecule will soon decay in a proton and a H-atom.
💬 Discuss
✅ Correct Answer: (C) the electrons, orbit would go around the protons.
Q. A set of atoms in an excited state decays
  • (A) in general to any of the states with lower energy.
  • (B) into a lower state only when excited by an external electric field.
  • (C) all together simultaneously into a lower state
  • (D) to emit photons only when they collide.
💬 Discuss
✅ Correct Answer: (A) in general to any of the states with lower energy.
Q. Two H atoms in the ground state collide inelastically. The maximum amount by which their combined kinetic energy is reduced is
  • (A) 10.20 eV
  • (B) 20.40 eV
  • (C) 13.6 eV
  • (D) 27.2 eV
💬 Discuss
✅ Correct Answer: (A) 10.20 eV
Q. 02 molecule consists of two oxygen atoms. In the molecule, nuclear force between the nuclei of the two atoms
  • (A) is not important because nuclear forces are short-ranged.
  • (B) is as important as electrostatic force for binding the two atoms.
  • (C) cancels the repulsive electrostatic force between the nuclei.
  • (D) is not important because oxygen nucleus has equal number of neutrons and protons.
💬 Discuss
✅ Correct Answer: (A) is not important because nuclear forces are short-ranged.
Q. For the ground state, the electron in the H-atom has an angular momentum = h, according to the simple Bohr model. Angular momentum is a vector and hence there will be infinitely many orbits with the vector pointing in all possible directions. In actuality, this is not true,
  • (A) because Bohr model gives incorrect values of angular momentum.
  • (B) because only one of these would have a minimum energy.
  • (C) angular momentum must be in the direction of spin of electron.
  • (D) because electrons go around only in horizontal orbits
💬 Discuss
✅ Correct Answer: (A) because Bohr model gives incorrect values of angular momentum.
Q. The simple Bohr model cannot be directly applied to calculate the energy levels of an atom with many electrons. This is because
  • (A) of screening effects.
  • (B) of the electrons colliding with each other.
  • (C) the force between the nucleus and an electron will no longer be given by Coulomb’s law.
  • (D) of the electrons not being subject to a central force.
💬 Discuss
✅ Correct Answer: (D) of the electrons not being subject to a central force.
Q. Taking the Bohr radius as a0 = 53 pm, the radius of Li++ ion in its ground state, on the basis of Bohr’s model, will be about
  • (A) 53 pm
  • (B) 27 pm
  • (C) 18 pm
  • (D) 13 pm
💬 Discuss
✅ Correct Answer: (C) 18 pm
Q. The spectral lines in the Brackett series arise due to transition of electron in hydrogen atom from higher orbits to the orbit with
  • (A) n = 1
  • (B) n = 2
  • (C) n = 3
  • (D) n = 4
💬 Discuss
✅ Correct Answer: (D) n = 4
Q. The transition of electron from n = 4, 5, 6, ………. to n = 3 corresponds to
  • (A) Lyman series
  • (B) Balmer series
  • (C) Paschen series
  • (D) Brackettseries
💬 Discuss
✅ Correct Answer: (C) Paschen series
Q. As per Bohr model, the minimum energy (in eV) required to remove an electron from the ground state of double ionized Li atom (Z = 3) is
  • (A) 1.51 eV
  • (B) 13.6 eV
  • (C) 40.8 eV
  • (D) 122.4 eV
💬 Discuss
✅ Correct Answer: (D) 122.4 eV
Q. Which of the following spectral series in hydrogen atom gives spectral line of 4860 A?
  • (A) Lyman
  • (B) Balmer
  • (C) Paschen
  • (D) Brackett
💬 Discuss
✅ Correct Answer: (B) Balmer
Q. The first model of atom in 1898 was proposed by
  • (A) Ernst Rutherford
  • (B) Albert Einstein
  • (C) J.J. Thomson
  • (D) Niels Bohr
💬 Discuss
✅ Correct Answer: (C) J.J. Thomson
Q. In Geiger-Marsden scattering experiment, the trajectory traced by an a-particle depends on
  • (A) number of collision
  • (B) number of scattered a-particles
  • (C) impact parameter
  • (D) none of these
💬 Discuss
✅ Correct Answer: (C) impact parameter
Q. In the Geiger-Marsden scattering experiment the number of scattered particles detected are maximum and minimum at the scattering angles respectively at
  • (A) 0° and 180°
  • (B) 180° and 0°
  • (C) 90° and 180°
  • (D) 45° and 90°
💬 Discuss
✅ Correct Answer: (A) 0° and 180°
Q. In the Geiger-Marsden scattering experiment, is case of head-on collision the impact parameter should be
  • (A) maximum
  • (B) minimum
  • (C) infinite
  • (D) zero
💬 Discuss
✅ Correct Answer: (A) maximum
Q. Rutherford’s experiments suggested that the size of the nucleus is about
  • (A) 10-14 m to 10-12 m
  • (B) 10-15 m to 10-13 m
  • (C) 10-15 m to 10-14 m
  • (D) 10-15 m to 10-12 m
💬 Discuss
✅ Correct Answer: (C) 10-15 m to 10-14 m
Q. Which of the following spectral series falls within the visible range of electromagnetic radiation?
  • (A) Lyman series
  • (B) Balmer series
  • (C) Paschen seriee
  • (D) Pfund series
💬 Discuss
✅ Correct Answer: (B) Balmer series
Q. The hydrogen atom can give spectral lines in the Lyman, Balmer and Paschen series. Which of the following statement is correct?
  • (A) Lyman series is in the infrared region.
  • (B) Balmer series is in the visible region.
  • (C) Paschen series is in the visible region.
  • (D) Balmer series is in the ultraviolet region.
💬 Discuss
✅ Correct Answer: (B) Balmer series is in the visible region.
Q. The transition from the state n = 5 to n = 1 in a hydrogen atom results in UV radiation. Infrared radiation will be obtained in the transition
  • (A) 2 → 1
  • (B) 3 → 2
  • (C) 4 → 3
  • (D) 6 → 2
💬 Discuss
✅ Correct Answer: (C) 4 → 3
Q. The diagram shows the energy levels for an electron in a certain atom. Which transition shown represents the emission of a photon with the most energy?
  • (A) I
  • (B) II
  • (C) III
  • (D) IV
💬 Discuss
✅ Correct Answer: (C) III
Q. If tt is the orbit number of the electron in a hydrogen atom, the correct statement among the following is
  • (A) electron energy increases as n increases.
  • (B) hydrogen emits infrared rays for the electron transition from n = to n = 1
  • (C) electron energy is zero for n = 1 (<0 electron energy varies as n2.
  • (D) None of these
💬 Discuss
✅ Correct Answer: (A) electron energy increases as n increases.
Q. The Bohr model of atoms
  • (A) assumes that the angular momentum of elec-trons is quantized.
  • (B) uses Einstein’s photoelectric equation.
  • (C) predicts continuous emission spectra for at-oms.
  • (D) predicts the same emission spectra for all types of atoms.
💬 Discuss
✅ Correct Answer: (A) assumes that the angular momentum of elec-trons is quantized.
Q. Which of the following postulates of the Bohr model led to the quantization of energy of the hydrogen atom?
  • (A) The electron goes around the nucleus in circular orbits.
  • (B) The angular momentum of the electron can only be an integral multiple of h/2π.
  • (C) The magnitude of the linear momentum of the electron is quantized.
  • (D) Quantization of energy is itself a postulate of the Bohr model.
💬 Discuss
✅ Correct Answer: (B) The angular momentum of the electron can only be an integral multiple of h/2π.
Q. The first spectral series was discovered by
  • (A) Balmer
  • (B) Lyman
  • (C) Paschen
  • (D) Pfund
💬 Discuss
✅ Correct Answer: (A) Balmer

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Table of contents

  1. If 13.6 eV energy is required to ionise the hydrogen atom, then energy required to remove an electro
  2. In Bohr’s model of an atom which of the following is an integral multiple of h2π?
  3. In Bohr’s model, the atomic radius of the first orbit is rQ. Then, the radius of the third orbit i
  4. The ratio between Bohr radii is
  5. The longest wavelength in Balmer series of hydrogen spectrum will be
  6. In terms of Rydberg constant R, the wave number of the first Balmer line is
  7. The ionisation energy of hydrogen atom is 13.6 eV. Following Bohr’s theory the energy correspondin
  8. On moving up in the energy states of a H-like atom, the energy difference between two consecutive en
  9. The Bohr model for the spectra of a H-atom
  10. Consider aiming a beam of free electrons towards free protons. When they scatter, an electron and a
  11. The binding energy of a H-atom, considering an electron moving around a fixed nuclei (proton), is B
  12. The electrons in the Bohr’s orbit have
  13. For ionising an exicited hydrogan atom, the energy required (in eV) will be
  14. The Bohr model of an atom
  15. Let En=−18ε20me4n2h2 be the energy of the nth level of H-atom. If all the H-atoms are in the grou
  16. The Balmer series for the H-atom can be observed
  17. An ionised H-molecule consists of an electron and two protons. The protons are separated by a small
  18. A set of atoms in an excited state decays
  19. Two H atoms in the ground state collide inelastically. The maximum amount by which their combined ki
  20. 02 molecule consists of two oxygen atoms. In the molecule, nuclear force between the nuclei of the t
  21. For the ground state, the electron in the H-atom has an angular momentum = h, according to the simpl
  22. The simple Bohr model cannot be directly applied to calculate the energy levels of an atom with many
  23. Taking the Bohr radius as a0 = 53 pm, the radius of Li++ ion in its ground state, on the
  24. The spectral lines in the Brackett series arise due to transition of electron in hydrogen atom from
  25. The transition of electron from n = 4, 5, 6, ………. to n = 3 corresponds to
  26. As per Bohr model, the minimum energy (in eV) required to remove an electron from the ground state o
  27. Which of the following spectral series in hydrogen atom gives spectral line of 4860 A?
  28. The first model of atom in 1898 was proposed by
  29. In Geiger-Marsden scattering experiment, the trajectory traced by an a-particle depends on
  30. In the Geiger-Marsden scattering experiment the number of scattered particles detected are maximum a
  31. In the Geiger-Marsden scattering experiment, is case of head-on collision the impact parameter shoul
  32. Rutherford’s experiments suggested that the size of the nucleus is about
  33. Which of the following spectral series falls within the visible range of electromagnetic radiation?
  34. The hydrogen atom can give spectral lines in the Lyman, Balmer and Paschen series. Which of the foll
  35. The transition from the state n = 5 to n = 1 in a hydrogen atom results in UV radiation. Infrared ra
  36. The diagram shows the energy levels for an electron in a certain atom. Which transition shown repres
  37. If tt is the orbit number of the electron in a hydrogen atom, the correct statement among the follow
  38. The Bohr model of atoms
  39. Which of the following postulates of the Bohr model led to the quantization of energy of the hydroge
  40. The first spectral series was discovered by